Casetta Lutron switches

I’m about to start installing some Casetta Lutron switches in our new house. Wondering if it’s possible to program the dimmer buttons to execute different scenes?

On the pico remote I know you can program the center button to execute scenes like movie night, etc but I’m wondering about the programmability of the other buttons.

The reason is I’m trying to decide where to place the remote vs the in wall switch for a three way switch. Ideally more buttons can be programmed so the one by the kitchen can controls lamps for scenes like movie night and the remote by the wall could turn on our outdoor hue lights.